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Syngas production from biomass pyrolysis followed by in-line biochar-catalytic reforming: the effect of space velocity, particle size, and morphology
KTH, School of Industrial Engineering and Management (ITM), Energy Technology, Heat and Power Technology.ORCID iD: 0000-0001-9884-1278
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Process.ORCID iD: 0000-0002-1709-5283
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Process.ORCID iD: 0000-0001-8160-6634
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Process.ORCID iD: 0000-0003-0583-9721
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2026 (English)In: Biomass and Bioenergy, ISSN 0961-9534, E-ISSN 1873-2909, Vol. 204, article id 108481Article in journal (Refereed) Published
Abstract [en]

A continuous pyrolysis combined with an in-line biochar-catalytic reforming of the pyrolysis vapor was investigated in a comprehensive system consisting of an auger reactor and a downstream fixed-bed reactor. The effect of the weight hourly space velocity (WHSV), particle size and morphology of biochar, and the pressure drop of the biochar bed on the catalytic performance were discussed in this study. Results showed that lower WHSV, which allows longer residence time, led to higher syngas yield and increased H2+CO proportion. The use of the smallest biochar particles (0.6-1 mm) produced the highest syngas and H2 yields, correlating with the greatest pressure drops. Spherical and rounded biochar particle shape enhanced syngas and H2 yields, as well as H2+CO proportions, due to improved heat and mass transfer. A maximum of 12 mmol H2/g-biomass was achieved, with a dry gas yield of 0.68 Nm3/kg, comprising 39 vol % H2 and 27 vol % CO, at the use of pelletized biochar with a WHSV of 0.51. The used biochar demonstrated stable catalytic performance as a reforming catalyst in a 100-min test period.

Place, publisher, year, edition, pages
Elsevier BV , 2026. Vol. 204, article id 108481
Keywords [en]
Biomass, Pyrolysis, Catalytic reforming, Biochar, Syngas, Auger
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:kth:diva-375084DOI: 10.1016/j.biombioe.2025.108481ISI: 001600262800006Scopus ID: 2-s2.0-105019507975OAI: oai:DiVA.org:kth-375084DiVA, id: diva2:2027664
Note

QC 20260113

Available from: 2026-01-13 Created: 2026-01-13 Last updated: 2026-01-13Bibliographically approved

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Yang, HanminWang, YazheJin, YanghaoBolívar Caballero, José JuanShi, ZiyiHan, TongSandström, LindaJönsson, Pär G.Yang, Weihong

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Yang, HanminWang, YazheJin, YanghaoBolívar Caballero, José JuanShi, ZiyiHan, TongSandström, LindaJönsson, Pär G.Yang, Weihong
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