kth.sePublications KTH
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Impact of zirconium incorporation on the thermophysical properties of uranium mononitride
KTH, School of Engineering Sciences (SCI), Physics, Nuclear Science and Engineering.ORCID iD: 0000-0002-0719-0893
KTH, School of Engineering Sciences (SCI), Physics, Nuclear Science and Engineering.
KTH, School of Engineering Sciences (SCI), Physics, Nuclear Science and Engineering.
KTH, School of Engineering Sciences (SCI), Physics, Nuclear Science and Engineering.ORCID iD: 0009-0004-8904-5543
Show others and affiliations
2026 (English)In: Journal of Nuclear Materials, ISSN 0022-3115, E-ISSN 1873-4820, Vol. 623, article id 156467Article in journal (Refereed) Published
Abstract [en]

Uranium mononitride (UN) is a promising candidate fuel for next-generation fast reactors due to its high fissile density, superior thermal conductivity, and high melting point compared to conventional oxide fuels. However, scarce experimental data on UN and its thermophysical behaviour under fission product incorporation limits its performance assessment. Zirconium nitride (ZrN) is an efficient thermal conductor and a candidate material for inert matrix fuels. Given its high thermal conductivity, ZrN addition at sufficient concentrations should, in principle, induce percolation conduction and increase thermal conductivity in UN. To decouple chemistry from irradiation-induced porosity, known to dominate thermal degradation at high burnup, this study isolates the intrinsic chemical contribution of Zr incorporation under dense, low-porosity conditions. (U,Zr)N pellets with 6.5 and 20 at. % Zr were fabricated by spark plasma sintering (SPS), using powders produced from arc-melted alloy via the hydride-nitride-denitride route. Synchrotron powder X-ray diffraction confirmed the formation of solid solutions and enhanced Zr solubility after sintering, resulting in improved microstructural homogeneity. Thermal diffusivity was measured between 300 and 1500 K using light flash analysis, and thermal conductivity was derived using heat capacity and density correlations with porosity correction. Despite the intrinsically higher thermal conductivity of ZrN, the incorporation of 6.5 at. % Zr reduced the thermal conductivity relative to UN, consistent with impurity scattering. The 20 at. % Zr composition further decreased conductivity, indicating the microstructure does not meet the conditions required for percolation conduction. Differences in the temperature dependence of thermal diffusivity between UN and Zr-bearing samples highlight a compositional influence on heat transport. The results provide benchmark data for (U,Zr)N and insights into chemical and thermophysical interactions in nitride ceramics.

Place, publisher, year, edition, pages
Elsevier BV , 2026. Vol. 623, article id 156467
Keywords [en]
Arc-melting, Light flash analysis, Spark plasma sintering, Synchrotron X-ray diffraction, Thermal conductivity, Uranium-zirconium nitride
National Category
Materials Chemistry Condensed Matter Physics
Identifiers
URN: urn:nbn:se:kth:diva-376522DOI: 10.1016/j.jnucmat.2026.156467ISI: 001676831400001Scopus ID: 2-s2.0-105028089939OAI: oai:DiVA.org:kth-376522DiVA, id: diva2:2036654
Note

QC 20260209

Available from: 2026-02-09 Created: 2026-02-09 Last updated: 2026-02-09Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records

Charatsidou, ElinaPazzaglia, AnitaGiamouridou, MariaJolkkonen, MikaelOlsson, Pär

Search in DiVA

By author/editor
Charatsidou, ElinaPazzaglia, AnitaBullock, KaitlynGiamouridou, MariaJolkkonen, MikaelOlsson, Pär
By organisation
Nuclear Science and Engineering
In the same journal
Journal of Nuclear Materials
Materials ChemistryCondensed Matter Physics

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 43 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf