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Revisiting applications of itaconic acid-based polymers obtained by (poly)condensation chemistry
Fraunhofer Institute for Wood Research – Wilhelm-Klauditz-Institut WKI, Riedenkamp 3, 38108 Braunschweig, Germany.
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Polymer Technology.ORCID iD: 0000-0003-0817-8148
Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, 16146, Genova (GE), Italy.
Fraunhofer Institute for Wood Research – Wilhelm-Klauditz-Institut WKI, Riedenkamp 3, 38108 Braunschweig, Germany.
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2026 (English)In: Green Chemistry, ISSN 1463-9262, E-ISSN 1463-9270, Vol. 28, no 14, p. 5910-5940Article, review/survey (Refereed) Published
Abstract [en]

For more than a decade, itaconic acid (methylene succinic acid) has been one of the most promising bio-based platform chemicals. The reliable availability in the market, combined with a competitive price, makes the implementation of this molecule as a building block very interesting, also from a commercial point of view. In addition, itaconic acid being exclusively produced by biotechnological processes, is not a mere drop-in molecule. As it is not commercially available via classical chemical routes, it does not compete with the exactly same and, in most cases, cheaper petroleum-based building blocks, which is usually very challenging. But even more important, itaconic acid allows for novel chemistries and applications that cannot be achieved with the established petroleum-based building blocks. In this respect, itaconic acid has been used as an alternative monomer in radical polymerization. However, since itaconic acid is a dicarboxylic acid, it has also been explored in polycondensation reactions with a wide range of applications, spanning unsaturated polyester resins, coatings, medical applications and additive manufacturing. This work critically reviews the progress in itaconic acid-derived (poly)condensation polymers since 2016. In addition, the sustainability of this promising building block is discussed.

Place, publisher, year, edition, pages
Royal Society of Chemistry (RSC) , 2026. Vol. 28, no 14, p. 5910-5940
National Category
Polymer Technologies
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URN: urn:nbn:se:kth:diva-379055DOI: 10.1039/d5gc06888fISI: 001715708200001PubMedID: 41852622Scopus ID: 2-s2.0-105033003285OAI: oai:DiVA.org:kth-379055DiVA, id: diva2:2051080
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QC 20260407

Available from: 2026-04-07 Created: 2026-04-07 Last updated: 2026-04-17Bibliographically approved

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Papadopoulos, LazarosHakkarainen, Minna

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