Capacitive deionization (CDI) is an emerging technique for purifying water by removing ions. Recent experimental studies have reported that the anion/cation adsorption can be naturally imbalanced, even for a solution with just sodium and chloride, and suggested a link between imbalance and Faradaic leakages. However, these effects have been missing from conventional models. In this work, we developed a new circuit model to better understand the connection between Faradaic leakages and adsorption imbalance. The theory demonstrates that the effect emerges in a model that includes leakages, considers leakages on both electrodes separately, and considers different leakage resistance on the two electrodes. Having the model, it is possible to analyze and quantify the influence of the leakage resistance and other material properties on the adsorption imbalance. Leveraging these results, we further present a multi-electrode (ME) device design. The setup adds a third electrode to the spacer channel and can tune or eliminate the adsorption imbalance based on appropriately distributing the voltage across the electrodes. In conclusion, we describe a charge leakage mechanism responsible for the imbalance of ion adsorption and a flexible device design to tune the anion/cation removal.