In this article, we consider an Industrial Internet of Things (IIoT) network operating under a carrier sense multiple access with collision avoidance (CSMA/CA) protocol. Latency-sensitive packets generated at multiple stations randomly are transmitted to a destination for decision making. To meet the strict timeliness constraint, the transmissions are carried by finite blocklength (FBL) codes, while the truncated hybrid automatic repeat request (HARQ) scheme is exploited to improve the reliability. For such unsaturated CSMA/CA networks, for the first time, we characterize the timeliness of packets utilized for decision-making via the age upon decisions (AuD) metric which emphasizes the information freshness at decision moments in comparison to age of information (AoI). To explicitly quantify the AuD performance, we develop an equivalent and tractable unsaturated Markov transfer model for the considered network and investigate the transmission probability and collision probability, respectively. Subsequently, the probability density functions of interarrival time and service time of the successfully transmitted packets are derived. We further derive a closed-form expression for the average AuD under a geometric decision process accordingly. Based on these characterizations, we aim at improving average AuD by jointly allocating the blocklength and transmit power. The formulated nonconvex problem is decomposed into subproblems, and we prove its joint convexity across all feasible intervals. Via simulations, we evaluate the performance of the considered network and conclude a series of design guidelines.