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Study of Translational Diffusion Anisotropy of Ionic Smectogens by NMR Diffusometry
KTH, Skolan för kemivetenskap (CHE), Kemi.
KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. St. Petersburg State University, Russian Federation.ORCID-id: 0000-0002-6524-1441
2015 (engelsk)Inngår i: Molecular Crystals and Liquid Crystals, ISSN 1542-1406, E-ISSN 1563-5287, Vol. 614, nr 1, s. 30-38Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Thermotropic ionic liquid crystals are considered very promising for a wide range of applications, such as anisotropic conductors as well as electrolytes in dye-synthesized solar cells. Their potential comes from the unique combination of ionic conductivity and high polarizability. In this paper we present a study of the diffusional properties of the ionic smectic A phase formed by the cationic smectogen, N-docecyl-N'-methyl-imidazolium (C12mim), with two different counter ions. Experimental translational diffusion data measured by NMR diffusometry are collected both for cations and anions and discussed in terms of their different anisotropy.

sted, utgiver, år, opplag, sider
2015. Vol. 614, nr 1, s. 30-38
Emneord [en]
Ionic Liquid Crystals, Diffusometry, NMR, Pulse Field Gradient NMR, Smectic, Dynamics
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Identifikatorer
URN: urn:nbn:se:kth:diva-173287DOI: 10.1080/15421406.2015.1049902ISI: 000359722500005Scopus ID: 2-s2.0-84939531529OAI: oai:DiVA.org:kth-173287DiVA, id: diva2:852573
Merknad

QC 20150909

Tilgjengelig fra: 2015-09-09 Laget: 2015-09-09 Sist oppdatert: 2022-06-23bibliografisk kontrollert

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Dvinskikh, Sergey V.

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Kharkov, Boris B.Dvinskikh, Sergey V.
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