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Regeneration of sulfur-poisoned Cu-SSZ-13 catalysts: Copper speciation and catalytic performance evaluation
Yale NUS Coll, Sci Div, Singapore 138527, Singapore..
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemiteknik, Processteknologi.ORCID-id: 0000-0002-5784-6686
Yale NUS Coll, Sci Div, Singapore 138527, Singapore..
ASTAR, Inst Chem & Engn Sci, Singapore 627833, Singapore..
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2021 (Engelska)Ingår i: Applied Catalysis B: Environmental, ISSN 0926-3373, E-ISSN 1873-3883, Vol. 299, artikel-id 120626Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Regeneration of a sulfur-poisoned Cu-SSZ-13 catalyst via a temperature ramp in an inert atmosphere with subsequent holding under oxidizing conditions at 500 degrees C restores significant activity for NOx conversion under standard, fast, and NO2-rich SCR conditions. The N2O selectivity of the regenerated catalyst is higher than for the fresh catalyst under NO2-rich SCR conditions at 280 degrees C, while the opposite was observed for the standard and fast SCR conditions. Analysis of copper speciation showed that sulfur-free Cu species have different conditiondependent behavior in the fresh and regenerated catalysts. Heating the poisoned catalyst in an oxidizing atmosphere transforms a portion of ammonium sulfates into stable metal sulfates, while heating under inert or reducing conditions leads to more effective desulfation without the formation of stable metal sulfates. Reducing conditions result in desulfation at lower temperatures compared to inert conditions. These results contribute to the further development of regeneration strategies for Cu-SSZ-13 catalysts.

Ort, förlag, år, upplaga, sidor
Elsevier BV , 2021. Vol. 299, artikel-id 120626
Nyckelord [en]
Cu-CHA, DeSOx, NH3-SCR, NO2, NOx ratio, N2O selectivity
Nationell ämneskategori
Kemiteknik
Identifikatorer
URN: urn:nbn:se:kth:diva-303747DOI: 10.1016/j.apcatb.2021.120626ISI: 000703891500005Scopus ID: 2-s2.0-85114418958OAI: oai:DiVA.org:kth-303747DiVA, id: diva2:1608165
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QC 20211103

Tillgänglig från: 2021-11-03 Skapad: 2021-11-03 Senast uppdaterad: 2025-02-18Bibliografiskt granskad

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Dahlin, SandraPettersson, Lars

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