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Characterization and formation mechanism of non-metallic inclusions in single bcc-phase high entropy alloy
KTH, Skolan för industriell teknik och management (ITM), Materialvetenskap, Processer. Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education & Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking, Wuhan University of Science and Technology, Wuhan 430081, China.ORCID-id: 0000-0001-7585-4674
KTH, Skolan för industriell teknik och management (ITM), Materialvetenskap.ORCID-id: 0000-0003-4438-8644
National Engineering Research Center for Magnesium Alloys & College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, China.
Department of Materials Science and Chemical Engineering, Hanyang University, Ansan 15588, Korea.
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2023 (Engelska)Ingår i: Materials Characterization, ISSN 1044-5803, E-ISSN 1873-4189, Vol. 205, artikel-id 113299Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

This work aims to provide a fundamental study of inclusion characteristics in the single bcc-phase high entropy alloy (HEA), Mn-rich and Al-contained multicomponent system (Al-Cr-Mn-Fe-Co-Ni) was selected as the prototype alloy in this study. According to the differential thermal analysis (DTA) measurements, the solidus (TS) and liquidus (TL) temperatures of this alloy were in the range of 1225–1228 °C (1226 ± 2 °C) and 1268–1271 °C (1270 ± 2 °C), respectively. Non-metallic inclusions were investigated in a two-dimensional (2D) cross-section method as well as extracted by a three-dimensional (3D) electrolytic extraction method. It was found that AlN was the dominant inclusion phase, also a small amount of Al2O3 inclusions were observed. They formed in the liquid alloy and mostly presented as Al2O3-AlN agglomerates, where the size range of the AlN inclusions was larger than that of Al2O3. The theoretical calculation showed that AlN inclusion has a higher coagulation coefficient and collision rate than those of Al2O3 inclusions, which agrees well with the experimental observations. The inclusion characteristics of Al2O3 and AlN were closely related to the relative contents of O and N in the presence of high Al content in the alloy. The impurity elements of N and O were the key issues in controling the stable inclusion phase in high entropic alloy.

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Elsevier BV , 2023. Vol. 205, artikel-id 113299
Nyckelord [en]
Body-centered cubic (bcc), Characterization, High entropy alloy, Kinetics, Non-metallic inclusion, Thermodynamics
Nationell ämneskategori
Metallurgi och metalliska material
Identifikatorer
URN: urn:nbn:se:kth:diva-337448DOI: 10.1016/j.matchar.2023.113299ISI: 001080078300001Scopus ID: 2-s2.0-85171341755OAI: oai:DiVA.org:kth-337448DiVA, id: diva2:1802973
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QC 20231006

Tillgänglig från: 2023-10-06 Skapad: 2023-10-06 Senast uppdaterad: 2023-10-31Bibliografiskt granskad

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Wang, YongLin, SenMu, Wangzhong

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