Accurate real material modeling is essential for structural dynamic analysis and design. Reliable structural parameters estimation, involving geometric and material parameters, is a key prerequisite, yet many existing methods primarily address homogenized material properties, which is inadequate for multilayer composites with complex geometrical core. To this end, this paper introduces a robust wave-based approach to structural parameter identification of individual layers, using only full-field displacement data. Specifically, the Algebraic K-Space Identification 2D technique (AKSI 2D) initially extracts wavenumber space (k-space) from measured structural responses, while surrogate optimization subsequently aligns this experimental k-space with the Wave Finite Element Method (WFEM)-derived numerical k-space to estimate structural parameters. The superiority of the proposed identification method stems from: (1) the ability of the AKSI 2D to automatically and accurately identify wavenumbers in any wave propagation direction from displacement fields on 2D grids, even in noisy environments, eliminating the need for complex filtering and specific point layouts; (2) the capacity of the WFEM in modeling wave propagation within multilayer structures with complex geometries, using unit cell-based operations within finite element software; and (3) the efficiency of the surrogate optimization in solving high-dimensional problems by finding the global minimum with high computational efficiency. To validate the accuracy of the proposed method, the structural parameters of each layer in two numerical cases, a four-layer laminated carbon fiber panel and a kelvin cell-based sandwich composite panel, are estimated. The inverted structural parameters show good agreement with the reference values, with an averaged relative error of less than 3.5%, even when a high level of white noise is added to the simulated displacement field. In addition, the structural parameters of a real parallelogram core sandwich panel is updated experimentally. These studies confirm that the proposed approach aligns with the intuitive decision-making of structural engineers for material characterization and modeling, offering adaptability for diverse structural design tasks.