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Effects of water soaking-drying cycles on thermally modified spruce wood-plastic composites
KTH, School of Architecture and the Built Environment (ABE), Civil and Architectural Engineering, Building Materials.ORCID iD: 0000-0002-7250-8693
KTH, School of Architecture and the Built Environment (ABE), Civil and Architectural Engineering, Building Materials.ORCID iD: 0000-0001-8514-5409
Univ Melbourne, Nanostruct Interfaces & Mat Sci NIMS Grp, Melbourne, Vic 3010, Australia..
Aalto Univ, Dept Chem & Met Engn, Espoo 00076, Finland..
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2020 (English)In: Wood and Fiber Science, ISSN 0735-6161, Vol. 52, no 1, p. 2-12Article in journal (Refereed) Published
Abstract [en]

The overall aim of this work was to gain more insight on the potential of modified wood (TMW) components for use in wood-thermoplastic composites (WPCs). Laboratory-scale TMWPCs were produced, and the effects of severe water soaking-drying cycles on the samples were studied. Water sorption behavior and resulting dimensional and micromorphological changes were also studied, and the results were compared with those of unmodified wood-plastic composites (UWPCs) used as control. The TMW was prepared by cutting a spruce board into half and subjecting one-half to an atmosphere of superheated steam at atmospheric pressure with a peak temperature of 210 degrees C, with the other unmodified wood (UW) half as a control. The TMW and UW components were then prepared by a Wiley mill and thereafter sifted into smaller (mesh 0.20-0.40 mm) and larger (mesh 0.40-0.63 mm) size fractions. A portion of the wood components were also subjected to hydrothermal extraction (HE). Composite samples with these different wood components, polypropylene (PP) matrix, and maleated PP (MAPP) as coupling agent (50/48/2 wood/PP/MAPP ratio by weight) were then prepared by using a Brabender mixer followed by hot pressing. The matching micromorphology of the composites before and after the soaking-drying cycles was analyzed using a surface preparation technique based on ultraviolet-laser ablation combined with scanning electron microscopy. The results of the water absorption tests showed, as hypothesized, a significantly reduced water absorption and resulting thickness swelling at the end of a soaking cycle for the TMWPCs compared with the controls (UWPCs). The water absorption was reduced with about 50-70% for TMWPC and 60-75% for HE-TMWPC. The thickness swelling for TMWPCs was reduced with about 40-70% compared with the controls. Similarly, the WPCs with HE-UW components absorbed about 20-45% less moisture and showed a reduced thickness swelling of about 25-40% compared with the controls. These observations also were in agreement with the micromorphology analysis of the composites before and after the moisture cycling which showed a more pronounced wood-plastic interfacial cracking (de-bonding) as well as other microstructure changes in the controls compared with those prepared with TMW and HE-UW components. Based on these observations, it is suggested that these potential bio-based building materials show increased potential durability for applications in harsh outdoor environments, in particular TMWPCs with a well-defined and comparably small size fractions of TMW components.

Place, publisher, year, edition, pages
SOC WOOD SCI TECHNOL , 2020. Vol. 52, no 1, p. 2-12
Keywords [en]
thermally modified wood (TMW), wood-plastic composite (WPC), water absorption, dimensional stability, dynamic mechanical analysis (DMA), micromorphology, scanning electron microscopy (SEM), UV-laser ablation
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:kth:diva-273529DOI: 10.22382/wfs-2020-002ISI: 000529410400010Scopus ID: 2-s2.0-85083033453OAI: oai:DiVA.org:kth-273529DiVA, id: diva2:1431054
Note

QC 20200519

Available from: 2020-05-19 Created: 2020-05-19 Last updated: 2022-06-26Bibliographically approved

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Källbom, SusannaLillqvist, KristiinaWålinder, Magnus

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