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Modification of softwood kraft pulp fibres using hydrogen peroxide at acidic conditions
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center.ORCID iD: 0000-0002-2501-9918
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center.ORCID iD: 0000-0002-2120-6513
2020 (English)In: Cellulose, ISSN 0969-0239, E-ISSN 1572-882X, Vol. 27, no 12, p. 7191-7202Article in journal (Refereed) Published
Abstract [en]

The aim of this work was to provide softwood kraft pulp fibres with new functionalities by the introduction of carbonyl groups. Carbonyl groups are known to affect properties such as wet strength through the formation of covalent bonds, i.e. hemiacetals. The method developed involves oxidation using hydrogen peroxide at mildly acidic conditions. It was found that the carbonyl group content increased with both increasing temperature and residence time when oxidized at acidic conditions. The number of carboxylic groups, however, remained approximately constant. There was virtually no increase in carbonyl groups when oxidation was performed at alkaline conditions. The maximum increase in carbonyl groups was found at a residence time of 90 min, a reaction temperature of 85 degrees C and a pH of 4. These conditions resulted in an increase in carbonyl groups from 30 to 122 mu mol/g. When formed into a sheet, the pulp oxidized at acidic conditions proved to maintain its structural integrity at aqueous conditions. This indicates the formation of hemiacetal bonds between the introduced carbonyl groups and the hydroxyl groups on the carbohydrate chains. Thus, a possible application for the method could be fibre modification during the final bleaching stage of softwood kraft pulp, where the wet strength of the pulp could be increased.

Place, publisher, year, edition, pages
SPRINGER , 2020. Vol. 27, no 12, p. 7191-7202
Keywords [en]
Hydrogen peroxide, Cellulose oxidation, Carbonyl groups, Wet strength, Bleaching
National Category
Paper, Pulp and Fiber Technology
Identifiers
URN: urn:nbn:se:kth:diva-278949DOI: 10.1007/s10570-020-03245-zISI: 000550541100033Scopus ID: 2-s2.0-85085372529OAI: oai:DiVA.org:kth-278949DiVA, id: diva2:1459944
Note

QC 20200821

Available from: 2020-08-21 Created: 2020-08-21 Last updated: 2022-06-26Bibliographically approved

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Hasani, MerimaTheliander, Hans

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