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Comparison of Theory and Experiments on van der Waals Forces in Media-A Survey
Albert Ludwigs Univ Freiburg, Phys Inst, D-79104 Freiburg, Germany..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science. KTH Royal Inst Technol, Appl Phys Chem, SE-10044 Stockholm, Sweden.;Australian Natl Univ, Res Sch Phys, Dept Appl Math, Canberra, ACT 2601, Australia..ORCID iD: 0000-0002-7461-2232
Albert Ludwigs Univ Freiburg, Phys Inst, D-79104 Freiburg, Germany..
Albert Ludwigs Univ Freiburg, Phys Inst, D-79104 Freiburg, Germany.;Univ Oslo, Ctr Mat Sci & Nanotechnol, Dept Phys, NO-0316 Oslo, Norway..
2020 (English)In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 124, no 44, p. 24179-24186Article in journal (Refereed) Published
Abstract [en]

We present a critical overview comparing theoretical predictions and measurements of van der Waals dispersion forces in media on the basis of the respective Hamaker constants. To quantify the agreement, we complement the reported experimental errors with those for the theoretical predictions, which are because of the uncertainties in the underlying spectroscopic data. Our main finding is that the theoretical errors are often larger than their experimental counterparts. Within these uncertainties, the comparison confirms the standard Lifshitz theory based on the Abraham electromagnetic stress tensor against the recently suggested alternative account on the basis of the Maxwell stress tensor.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2020. Vol. 124, no 44, p. 24179-24186
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-288440DOI: 10.1021/acs.jpcc.0c06748ISI: 000589917300017Scopus ID: 2-s2.0-85096040354OAI: oai:DiVA.org:kth-288440DiVA, id: diva2:1524484
Note

QC 20210201

Available from: 2021-02-01 Created: 2021-02-01 Last updated: 2022-06-25Bibliographically approved

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Corkery, Robert

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