This paper reports preliminary results of the DESPEC campaign at GSI, focused on the study of neutron-deficient nuclei approaching Sn-100. The results presented show the isomeric decays of excited states with I-pi = 14(+) and 8(+) in Pd-96 and Pd-94, respectively. The detailed characterisation of the DESPEC set-up and analysis methodologies, proven in this experimental run, are crucial for the future campaigns.