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Origin of anomalously stabilizing ice layers on methane gas hydrates near rock surface
Nanchang Univ, Sch Phys & Mat Sci, Nanchang 330031, Peoples R China.;Nanchang Univ, Inst Space Sci & Technol, Nanchang 330031, Peoples R China..ORCID iD: 0000-0001-5973-8980
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science. Australian Natl Univ, Res Sch Phys & Engn, Appl Math Dept, Acton, ACT 2610, Australia..ORCID iD: 0000-0002-7461-2232
Univ Autonoma Madrid, Dept Fis Mat, Madrid 28049, Spain.;Univ Autonoma Madrid, Inst Ciencia Mat Nicolas Cabrera, Madrid 28049, Spain..
Norwegian Univ Life Sci, Fac Sci & Technol, As, Norway..ORCID iD: 0000-0002-4655-1233
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2023 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 25, no 9, p. 6636-6652Article in journal (Refereed) Published
Abstract [en]

Gas hydrates (GHs) in water close to freezing temperatures can be stabilised via the formation of ice layers. In a recent work [Bostrom et al., Astron. Astrophys., A54, 650, 2021], it was found that a surface region with partial gas dilution could be essential for obtaining nano- to micron-sized anomalously stabilizing ice layers. In this paper, it is demonstrated that the Casimir-Lifshitz free energy in multi-layer systems could induce thinner, but more stable, ice layers in cavities than those found for gas hydrates in a large reservoir of cold water. The thickness and stability of such ice layers in a pore filled with cold water could influence the leakage of gas molecules. Additional contributions, e.g. from salt-induced stresses, can also be of importance, and are briefly discussed.

Place, publisher, year, edition, pages
Royal Society of Chemistry (RSC) , 2023. Vol. 25, no 9, p. 6636-6652
National Category
Astronomy, Astrophysics and Cosmology
Identifiers
URN: urn:nbn:se:kth:diva-324816DOI: 10.1039/d2cp04883cISI: 000933359400001PubMedID: 36790196Scopus ID: 2-s2.0-85149002122OAI: oai:DiVA.org:kth-324816DiVA, id: diva2:1744764
Note

QC 20230320

Available from: 2023-03-20 Created: 2023-03-20 Last updated: 2023-03-20Bibliographically approved

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Corkery, Robert

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