Origin of anomalously stabilizing ice layers on methane gas hydrates near rock surfaceShow others and affiliations
2023 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 25, no 9, p. 6636-6652Article in journal (Refereed) Published
Abstract [en]
Gas hydrates (GHs) in water close to freezing temperatures can be stabilised via the formation of ice layers. In a recent work [Bostrom et al., Astron. Astrophys., A54, 650, 2021], it was found that a surface region with partial gas dilution could be essential for obtaining nano- to micron-sized anomalously stabilizing ice layers. In this paper, it is demonstrated that the Casimir-Lifshitz free energy in multi-layer systems could induce thinner, but more stable, ice layers in cavities than those found for gas hydrates in a large reservoir of cold water. The thickness and stability of such ice layers in a pore filled with cold water could influence the leakage of gas molecules. Additional contributions, e.g. from salt-induced stresses, can also be of importance, and are briefly discussed.
Place, publisher, year, edition, pages
Royal Society of Chemistry (RSC) , 2023. Vol. 25, no 9, p. 6636-6652
National Category
Astronomy, Astrophysics and Cosmology
Identifiers
URN: urn:nbn:se:kth:diva-324816DOI: 10.1039/d2cp04883cISI: 000933359400001PubMedID: 36790196Scopus ID: 2-s2.0-85149002122OAI: oai:DiVA.org:kth-324816DiVA, id: diva2:1744764
Note
QC 20230320
2023-03-202023-03-202023-03-20Bibliographically approved