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Optimization of on-site wastewater treatment efficiency and recovery based on nutrient mobility and adsorption kinetics modelling using HYDRUS-2D coupled with PHREEQC
KTH, School of Architecture and the Built Environment (ABE), Sustainable development, Environmental science and Engineering, Water and Environmental Engineering.ORCID iD: 0000-0002-8957-6772
KTH, School of Architecture and the Built Environment (ABE), Sustainable development, Environmental science and Engineering, Water and Environmental Engineering.ORCID iD: 0000-0002-7239-7321
KTH, School of Architecture and the Built Environment (ABE), Sustainable development, Environmental science and Engineering, Water and Environmental Engineering.ORCID iD: 0000-0001-6617-4001
KTH, School of Architecture and the Built Environment (ABE), Sustainable development, Environmental science and Engineering, Resources, Energy and Infrastructure.ORCID iD: 0000-0003-2726-6821
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2024 (English)In: Chemical Engineering Journal, ISSN 1385-8947, E-ISSN 1873-3212, Vol. 492, article id 152308Article in journal (Refereed) Published
Abstract [en]

A closed-loop on-site wastewater treatment system (OWT) was studied comprising steps of septic tank to remove organics (Biological Oxygen Demand (BOD)), biofiltration clarifier for biological removal of nitrogen (N), phosphorus (P) and BOD, reactive Polonite® filter for chemical adsorption and precipitation removal of dissolved P, and tidal flow constructed wetland (TFCW) sand filter for polishing the effluent to low P and N effluent Swedish standards. The field experimental data that have been used to optimize TFCW design in the numerical modelling using HYDRUS-2D coupled with and without PHREEQC indicated that the adsorption efficiency of the reactive Polonite® adsorbent was nearly double to that obtained in TFCW sand filters for PO4-P (95 %) and Total-P (85 %) removal in summer at a high temperature range (15.4–18.8 °C) and pH range (9.9–10.8). The weaker PO4-P (53 %) and Total-P (25 %) removal efficiency in winter was due to a low temperature (1.5–8.1 °C) and low pH (7.2–7.9). This decrease in pH was attributed to salinity in the domestic wastewater and dilution of rainwater. Modelling results revealed that the transport mechanisms and rate of P adsorption kinetics in the TFCW sand filters enhanced with calcium and iron flow from chemical dissolution in the preceding Polonite® adsorbent was increased with the increase in temperature. However, the P adsorption was less sensitive at high ferrihydrite (Fe(OH)3) dose, suggesting limited effects of cations dissolution and abundance of metal oxides and hydroxide ions at the mineral surface for anions exchange with phosphate for surface complexation. The strategy of combining field data and modelling provided valuable insights for assessing adaptability and optimizing TFCW design under variable fluxes and scenario effects of insulated/uninsulated and dilution by rainwater in cold-climate regions.

Place, publisher, year, edition, pages
Elsevier BV , 2024. Vol. 492, article id 152308
Keywords [en]
Hydrogeochemical modelling, Nitrogen, Optimization, Phosphorus, Tidal flow constructed wetland
National Category
Water Engineering
Identifiers
URN: urn:nbn:se:kth:diva-347045DOI: 10.1016/j.cej.2024.152308ISI: 001265944300001Scopus ID: 2-s2.0-85193900296OAI: oai:DiVA.org:kth-347045DiVA, id: diva2:1862773
Note

QC 20240531

Available from: 2024-05-30 Created: 2024-05-30 Last updated: 2024-08-20Bibliographically approved

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Hamisi, RajabuRenman, AgnieszkaRenman, GunnoWörman, AndersThunvik, Roger

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CiteExportLink to record
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Citation style
  • apa
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