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The influence of Nickel on the corrosion protection of FeCrNi alloys after breakaway corrosion at 600 °C
Division of Energy and Materials, Chalmers University of Technology, Gothenburg, Sweden.ORCID iD: 0000-0001-5216-5673
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Structures.ORCID iD: 0000-0001-8797-4585
Valmet AB, SE-402 75, Sweden.
Höganäs AB, SE-263 83, Sweden.
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2024 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 240, article id 112473Article in journal (Refereed) Published
Abstract [en]

Breakaway corrosion of stainless steels remains a challenge for many industrial applications operating in harsh conditions. The lifetimes of metallic components are often determined by the corrosion propagation after breakaway. Nevertheless, studies on the protective properties of the Fe-rich oxides formed after breakaway are scarce. This study investigates the influence of Ni on the protection after breakaway on a broad range of Fe18CrxNi model alloys, by systematically inducing breakaway of the initially formed protective, Cr-rich oxides. The results clearly demonstrate an improved protection after breakaway for higher Ni-contents, explained by the alloys’ ability to avoid internal oxidation involving Fe-rich BCC and spinel.

Place, publisher, year, edition, pages
Elsevier BV , 2024. Vol. 240, article id 112473
Keywords [en]
Breakaway corrosion, High temperature corrosion, Internal oxidation, Nickel, Secondary corrosion protection, Stainless steels
National Category
Metallurgy and Metallic Materials Surface- and Corrosion Engineering
Identifiers
URN: urn:nbn:se:kth:diva-354642DOI: 10.1016/j.corsci.2024.112473ISI: 001368437500001Scopus ID: 2-s2.0-85205288881OAI: oai:DiVA.org:kth-354642DiVA, id: diva2:1904538
Note

QC 20250120

Available from: 2024-10-09 Created: 2024-10-09 Last updated: 2025-02-09Bibliographically approved

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Larsson, Henrik

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CiteExportLink to record
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  • apa
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