This study introduces a novel energy conversion and management framework to reduce carbon emissions in the energy sector and expedite the global shift towards sustainable practices. The system is driven by biomass-based solid oxide fuel cells for efficient power generation. Central to this approach lies the integration of additional hydrogen injection provided by a thermally-driven vanadium chloride cycle, aiming to enhance the quality of the syngas entering the fuel cells. The system is also combined with a super-critical CO2 cycle that generates power by passively enhancing performance through flue gas condensation. The proposed model's feasibility is evaluated in depth, techno-economically, considering thermodynamics and specific cost theories. As part of artificial intelligence, a neural network model is coupled with the genetic algorithm to determine the best operating status while minimizing computation time. According to the results, the suggested new integration results in higher efficiency and lower cost than a similar system without hydrogen injection. The results further show that the triple-objective optimization achieves output power, second-law efficiency, and overall system cost of 3425 kW, 48.5 %, and 2.3 M$/year, respectively. Eventually, the gasifier is the main contributor to the highest level of exergy destruction, and fuel utilization and current density are the most important parameters in modeling.