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Recyclable electroactive paper based on cationic fibers adaptable to industrial papermaking
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fibre Technology.ORCID iD: 0000-0003-0298-8553
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fibre Technology.ORCID iD: 0000-0002-9113-8413
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fiberprocesser.ORCID iD: 0000-0002-9201-0454
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fibre Technology.ORCID iD: 0000-0002-1535-9476
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2024 (English)In: Cellulose, ISSN 0969-0239, E-ISSN 1572-882X, Vol. 31, no 14, p. 8837-8849Article in journal (Refereed) Published
Abstract [en]

Paper is the largest renewable industrial substrate produced for various applications and can be recycled by disintegrating the fibers and reforming the paper. Paper and its fiber constituents lack functions such as electrical conductivity and papermaking itself has not been used for producing electronic devices. In this work, we show a potential industrially viable route for introducing cationic charges on the cellulose fibers and subsequently show how the adsorption of negatively charged ionically and electrically conductive materials onto these fibers from aqueous media can be applied at time scales relevant to industrial papermaking. This results in electroactive fibers, that can subsequently be used to prepare electroactive papers using standard papermaking procedures. Since fibers in the paper can selectively be coated with different active materials, various functions can be added into the paper. To demonstrate applications, we prepared electroactive papers using fibers with adsorbed carbon nanotubes (CNTs) and conducting polymers. We achieved conductivity of 21 S/m with only 1wt% CNT. We also prepared papers with CNTs and black phosphorus, used as paper-based lithium, and sodium ion battery (free-standing) anodes. They delivered a specific capacity of 642 mA h g<sup>−1</sup> at 100 mA g<sup>−1</sup> after 3500 cycles with 99.5% columbic efficiency. Furthermore, we recycled the papers, and as the disintegration of the fibers did not lead to removal of the ionic or electroactive materials from the fiber surface, the recycled papers showed similar electrical and mechanical properties to the original papers. This opens the path for recyclable paper-based electronics.

Place, publisher, year, edition, pages
Springer Nature , 2024. Vol. 31, no 14, p. 8837-8849
Keywords [en]
Adsorption, Battery, Composite, Fiber, Paper, Recycle
National Category
Paper, Pulp and Fiber Technology Materials Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-366596DOI: 10.1007/s10570-024-06128-9ISI: 001298725100001Scopus ID: 2-s2.0-85202028982OAI: oai:DiVA.org:kth-366596DiVA, id: diva2:1983407
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QC 20250710

Available from: 2025-07-10 Created: 2025-07-10 Last updated: 2025-07-10Bibliographically approved

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Hajian, AlirezaJain, KarishmaKilic, Nuzhet InciIakunkov, ArtemSubramaniyam, Chandrasekar M.Wågberg, LarsLarsson, Per A.Hamedi, Mahiar

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Hajian, AlirezaJain, KarishmaKilic, Nuzhet InciIakunkov, ArtemSubramaniyam, Chandrasekar M.Wågberg, LarsLarsson, Per A.Hamedi, Mahiar
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Fibre TechnologyFiberprocesser
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Cellulose
Paper, Pulp and Fiber TechnologyMaterials Chemistry

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