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Translucent Biocomposites from Hot-Pressed Wood Fibers and Poly(limonene acrylate)
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Biocomposites. KTH Royal Inst Technol, Wallenberg Wood Sci Ctr, Dept Fibre & Polymer Technol, S-10044 Stockholm, Sweden.ORCID iD: 0000-0002-2984-7702
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Biocomposites. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center.ORCID iD: 0000-0001-6017-1774
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Biocomposites.ORCID iD: 0000-0003-2168-4504
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center.ORCID iD: 0000-0001-8181-8493
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2025 (English)In: ACS Applied Materials and Interfaces, ISSN 1944-8244, E-ISSN 1944-8252Article in journal (Refereed) Published
Abstract [en]

Translucent wood fiber composites offer new functions to stiff composites. Most "eco-friendly" thermoset resins are only partially biobased. Poly(limonene acrylate), PLIMA, can be fully biobased and is combined with hot-pressed softwood fibers (WF) by liquid resin impregnation and curing. Fibers are random-in-plane or strongly oriented and have different lignin characteristics. Microstructure-mechanical property relationships are compared for hot-pressed WF networks and WF/PLIMA biocomposites from the same fibers. Stress transfer in WF/PLIMA biocomposites is enhanced with a modulus of up to 16.7 GPa and a tensile strength of up to 139 MPa, compared to transparent plastics like poly(methyl methacrylate) (modulus similar to 3 GPa, tensile strength similar to 70 MPa). Optical transmittance is high, even at 35 vol % fiber content, suggesting translucent panels or lighting applications. Eco-indicators show that the PLIMA matrix accounts for similar to 80% of biocomposite cumulative energy demand (CED, cradle to gate) of 60 MJ/kg, compared to similar to 120 MJ/kg for glass fiber/thermoset composites.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2025.
Keywords [en]
transparent biocomposites, pulp fibers, biobasedthermoset, hot-pressed fibers, optical transmittance, eco-indicators
National Category
Composite Science and Engineering
Identifiers
URN: urn:nbn:se:kth:diva-371901DOI: 10.1021/acsami.5c07130ISI: 001532246200001PubMedID: 40686486Scopus ID: 2-s2.0-105012785671OAI: oai:DiVA.org:kth-371901DiVA, id: diva2:2007933
Note

QC 20251021

Available from: 2025-10-21 Created: 2025-10-21 Last updated: 2025-10-21Bibliographically approved

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Oliaei, ErfanMontanari, CelineLi, LengwanChen, HuiOlsen, PeterBerglund, Lars

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