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2024 (English)In: Carbon Energy, E-ISSN 2637-9368, Vol. 6, no 5, article id e442Article in journal (Refereed) Published
Abstract [en]
MXene is a promising energy storage material for miniaturized microbatteries and microsupercapacitors (MSCs). Despite its superior electrochemical performance, only a few studies have reported MXene-based ultrahigh-rate (>1000 mV s−1) on-paper MSCs, mainly due to the reduced electrical conductance of MXene films deposited on paper. Herein, ultrahigh-rate metal-free on-paper MSCs based on heterogeneous MXene/poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)-stack electrodes are fabricated through the combination of direct ink writing and femtosecond laser scribing. With a footprint area of only 20 mm2, the on-paper MSCs exhibit excellent high-rate capacitive behavior with an areal capacitance of 5.7 mF cm−2 and long cycle life (>95% capacitance retention after 10,000 cycles) at a high scan rate of 1000 mV s−1, outperforming most of the present on-paper MSCs. Furthermore, the heterogeneous MXene/PEDOT:PSS electrodes can interconnect individual MSCs into metal-free on-paper MSC arrays, which can also be simultaneously charged/discharged at 1000 mV s−1, showing scalable capacitive performance. The heterogeneous MXene/PEDOT:PSS stacks are a promising electrode structure for on-paper MSCs to serve as ultrafast miniaturized energy storage components for emerging paper electronics.
Place, publisher, year, edition, pages
Wiley, 2024
Keywords
direct ink writing, femtosecond laser scribing, MXene, on-paper microsupercapacitors, PEDOT:PSS, ultrahigh rate capability
National Category
Materials Chemistry Other Physics Topics
Identifiers
urn:nbn:se:kth:diva-366936 (URN)10.1002/cey2.442 (DOI)001141771500001 ()2-s2.0-85182185270 (Scopus ID)
Note
QC 20250711
2025-07-112025-07-112025-12-05Bibliographically approved