kth.sePublications KTH
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Regeneration of sulfur-poisoned Cu-SSZ-13 catalysts: Copper speciation and catalytic performance evaluation
Yale NUS Coll, Sci Div, Singapore 138527, Singapore..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemical Engineering, Process Technology.ORCID iD: 0000-0002-5784-6686
Yale NUS Coll, Sci Div, Singapore 138527, Singapore..
ASTAR, Inst Chem & Engn Sci, Singapore 627833, Singapore..
Show others and affiliations
2021 (English)In: Applied Catalysis B: Environmental, ISSN 0926-3373, E-ISSN 1873-3883, Vol. 299, article id 120626Article in journal (Refereed) Published
Abstract [en]

Regeneration of a sulfur-poisoned Cu-SSZ-13 catalyst via a temperature ramp in an inert atmosphere with subsequent holding under oxidizing conditions at 500 degrees C restores significant activity for NOx conversion under standard, fast, and NO2-rich SCR conditions. The N2O selectivity of the regenerated catalyst is higher than for the fresh catalyst under NO2-rich SCR conditions at 280 degrees C, while the opposite was observed for the standard and fast SCR conditions. Analysis of copper speciation showed that sulfur-free Cu species have different conditiondependent behavior in the fresh and regenerated catalysts. Heating the poisoned catalyst in an oxidizing atmosphere transforms a portion of ammonium sulfates into stable metal sulfates, while heating under inert or reducing conditions leads to more effective desulfation without the formation of stable metal sulfates. Reducing conditions result in desulfation at lower temperatures compared to inert conditions. These results contribute to the further development of regeneration strategies for Cu-SSZ-13 catalysts.

Place, publisher, year, edition, pages
Elsevier BV , 2021. Vol. 299, article id 120626
Keywords [en]
Cu-CHA, DeSOx, NH3-SCR, NO2, NOx ratio, N2O selectivity
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:kth:diva-303747DOI: 10.1016/j.apcatb.2021.120626ISI: 000703891500005Scopus ID: 2-s2.0-85114418958OAI: oai:DiVA.org:kth-303747DiVA, id: diva2:1608165
Note

QC 20211103

Available from: 2021-11-03 Created: 2021-11-03 Last updated: 2025-02-18Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records

Dahlin, SandraPettersson, Lars

Search in DiVA

By author/editor
Dahlin, SandraPettersson, Lars
By organisation
Process Technology
In the same journal
Applied Catalysis B: Environmental
Chemical Engineering

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 118 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf