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Kinetic studies of oxidation of MgAlON and a comparison of the oxidation behaviour of AlON, MgAlON, O'SiAlON-ZrO2, and BN-ZCM ceramics
KTH.
Univ Sci & Technol Beijing USTB, Dept Phys Chem, Beijing, Peoples R China..
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering.ORCID iD: 0000-0003-4695-9308
2022 (English)In: International Journal of Materials Research - Zeitschrift für Metallkunde, ISSN 1862-5282, E-ISSN 2195-8556, Vol. 93, no 6, p. 545-553Article in journal (Refereed) Published
Abstract [en]

The kinetics and morphology of the oxidation process of magnesium-aluminium oxynitride (MgAlON), aluminium oxynitride (AlON), 0' SiAlON-ZrO2, and BN-ZCM have been studied in the temperature range 1373-1773 K. Oxidation experiments with powder and plate samples of the above materials have been carried out in air. MgAlON shows the best resistance to oxidation at lower temperatures (<1473 K), whereas at higher temperatures (similar to 773 K), AlON shows the best resistance. O'SiAlON-ZrO2 shows very good oxidation resistance up to 1673 K. But its oxidation rate increases strongly above 1673 K, presumably due to the formation of liquid phase. BN-ZCM has the poorest oxidation resistance due to the evaporation of B2O3. The activation energies for the chemical oxidation reaction of AlON, MgAlON, and O'SiAlON-ZrO2 are 214, 330 and 260 kJ/mol, respectively. The overall diffusion activation energies for AlON, MgAlON, O'SiAlON-ZrO2 and BN-ZCM are 227, 573, 367 and 289 kJ/mol, respectively.

Place, publisher, year, edition, pages
WALTER DE GRUYTER GMBH , 2022. Vol. 93, no 6, p. 545-553
Keywords [en]
Oxidation, MgAlON, Kinetics, Morphology
National Category
Metallurgy and Metallic Materials
Identifiers
URN: urn:nbn:se:kth:diva-307309ISI: 000738547000009OAI: oai:DiVA.org:kth-307309DiVA, id: diva2:1630812
Note

QC 20220121

Available from: 2022-01-21 Created: 2022-01-21 Last updated: 2022-06-25Bibliographically approved

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Seetharaman, Seshadri

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