kth.sePublications KTH
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
The impact of ligands on the synthesis and application of metal halide perovskite nanocrystals
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Applied Physical Chemistry.ORCID iD: 0000-0002-7836-6649
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Applied Physical Chemistry.ORCID iD: 0000-0002-4782-4969
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Applied Physical Chemistry.ORCID iD: 0000-0002-9432-3112
2021 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, E-ISSN 2050-7496, Vol. 9, no 41, p. 23419-23443Article in journal (Refereed) Published
Abstract [en]

Metal halide perovskites have emerged as attractive materials for use in solar cells, light emitting diodes and other optoelectronic devices, mainly due to their impressive charge transport properties, strong light absorption, long carrier diffusion lengths and long excited state lifetime. The extensive research on these materials has paved the way for a new class of materials: metal halide perovskite nanocrystals (NCs). Due to their high photoluminescence quantum yield and narrow emission that can be tuned by size and compositional variations, perovskite NCs are considered to be ideal candidates compared to traditional quantum dots. With the growing interest in these materials and the current challenges in their commercialization, this review aims mainly to provide the necessary understanding of the influence of capping ligands on the synthesis and application of perovskite NCs. The different synthetic approaches and the role of ligands in determining the morphological and optical properties of the resulting NCs will be discussed. Thereafter, we review the advances in understanding the surface chemistry and ligation in the metal halide perovskite NCs. Lastly, we review the ligand exchange and management processes that are shown to be beneficial in improving the performance and stability of perovskite nanocrystal films for optoelectronic applications.

Place, publisher, year, edition, pages
Royal Society of Chemistry (RSC) , 2021. Vol. 9, no 41, p. 23419-23443
Keywords [en]
Chelation, Excited states, Ligands, Light absorption, Metal halides, Metals, Optical properties, Optoelectronic devices, Perovskite, Perovskite solar cells, Semiconductor quantum dots, Surface chemistry, 'current, Carrier diffusion length, Charge transport properties, Compositional variation, Excited state lifetimes, Halide perovskites, Lightemitting diode, Other opto-electronic devices, Photoluminescence quantum yields, Size variation, Nanocrystals
National Category
Theoretical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-313134DOI: 10.1039/d1ta05242jISI: 000708112100001Scopus ID: 2-s2.0-85118459597OAI: oai:DiVA.org:kth-313134DiVA, id: diva2:1670099
Note

QC 20220615

Available from: 2022-06-15 Created: 2022-06-15 Last updated: 2022-09-23Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records

Haydous, FatimaGardner, James M.Cappel, Ute B.

Search in DiVA

By author/editor
Haydous, FatimaGardner, James M.Cappel, Ute B.
By organisation
Applied Physical Chemistry
In the same journal
Journal of Materials Chemistry A
Theoretical Chemistry

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 86 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf