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Coincidence spectroscopy of molecular normal Auger decay by ultrashort x-ray pulses
Shaanxi Normal Univ, Sch Phys & Informat Technol, Xian 710119, Peoples R China..
Shaanxi Normal Univ, Sch Phys & Informat Technol, Xian 710119, Peoples R China..
ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Theoretical Chemistry and Biology.ORCID iD: 0000-0003-1269-8760
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2022 (English)In: Physical Review A: covering atomic, molecular, and optical physics and quantum information, ISSN 2469-9926, E-ISSN 2469-9934, Vol. 106, no 2, article id 023105Article in journal (Refereed) Published
Abstract [en]

When a core-shell electron is ionized by coherent ultrashort x-ray pulses with varied duration, different nuclear wave packets of a cationic molecule are formed, which can be effectively studied by detecting the photoelectron -Auger electron-ion fragment as it is proposed in the present paper. We develop the theory for the photoelectron, i.e., Auger electron, ion fragment three-body coincidence spectroscopy, where dissociative Auger final states are considered. Simulations to display the HF molecule show that the coincidence spectra encode the detailed information of coherent nuclear wave-packet dynamics. Our work paves the way for using currently available coherent ultrashort x-ray pulses to investigate and manipulate molecular nuclear wave packets. Moreover, we discuss possibilities for high-resolution coincidence experimental techniques.

Place, publisher, year, edition, pages
American Physical Society (APS) , 2022. Vol. 106, no 2, article id 023105
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:kth:diva-317203DOI: 10.1103/PhysRevA.106.023105ISI: 000842930400005Scopus ID: 2-s2.0-85135896027OAI: oai:DiVA.org:kth-317203DiVA, id: diva2:1694905
Note

QC 20220912

Available from: 2022-09-12 Created: 2022-09-12 Last updated: 2022-09-12Bibliographically approved

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Kimberg, Victor

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