Cyber-physical systems (CPS) offer integrated resolutions for various applications by combining computer and physical components and enabling individual machines to work together for much more excellent benefits. The ad hoc-based CPS provides a promising architecture due to its decentralized nature and destructiveresistance. A growing number of information leakage events in CPSs and the following serious consequences have aroused ubiquitous concern about information security. In this article, we combine physical layer security solutions and millimeter-wave (mmWave) techniques to safeguard the ad hoc network and investigate the reliability-security tradeoff by taking user demands for the network into account, where eavesdroppers attempt to intercept messages. For the secrecy enhancements, we adopt an artificial noise (AN) assisted transmission scheme, in which AN is employed to create non-cancellable interference to eavesdroppers. The reliability and security are correspondingly characterized by the connection outage probability and secrecy outage probability, and their analytical expressions of them are attained through theoretical analysis for the purpose of the tradeoff issue discussion. Our results reveal that secrecy performance in mmWave ad hoc networks gains significant improvement through the use of AN. It also shows that given total transmit power, there exists a tradeoff between reliability and security to achieve optimal outage performance.