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Roundly exploring the synthesis, structural design, performance modification, and practical applications of silicon-carbon composite anodes for lithium-ion batteries
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering. School of Materials Science and Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, PR China; Department of Materials Science and Engineering, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden; School of Materials Science and Engineering, Chongqing University, Chongqing 400044, PR China.ORCID iD: 0000-0001-6809-9092
School of Materials Science and Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, PR China.
School of Materials Science and Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, PR China.
School of Materials Science and Engineering, Chongqing University, Chongqing 400044, PR China.
2024 (English)In: Journal of Energy Storage, ISSN 2352-152X, E-ISSN 2352-1538, Vol. 101, article id 113794Article, review/survey (Refereed) Published
Abstract [en]

Silicon-based anode materials will replace traditional graphite anode materials and become one of the most promising anode materials for the next generation of lithium-ion batteries due to their high theoretical lithium storage capacity. However, silicon-based anodes have disadvantages such as large volume expansion effect, low first coulombic efficiency, low conductivity, and unstable solid electrolyte interface film, which lead to poor cycle stability of silicon-based anodes and seriously hinder their practical application. In order to better address these defects of silicon anodes, the more effective way at present is to use carbon with good stability and high conductivity to modify silicon-based anodes, and prepare silicon‑carbon composite anodes. This way, silicon-carbon anodes, as a material with high theoretical capacity, are expected to have large-scale commercial prospects. This review comprehensively explores the synthesis method, structural design, performance modification, and applications prospect of silicon‑carbon composite anodes. Its main purpose is to propose feasible strategies for the development of new preparation technology, nanostructural design, modification of electrode performance, and future commercial applications of silicon-carbon anodes. Additionally, this article also reveals the limitations of existing silicon-carbon composite anode materials, and the possible solving approach are also proposed to improve the comprehensive electrochemical performance of lithium-ion batteries.

Place, publisher, year, edition, pages
Elsevier BV , 2024. Vol. 101, article id 113794
Keywords [en]
Lithium-ion batteries, Performance modification, Silicon carbon anodes, Structural design
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-353970DOI: 10.1016/j.est.2024.113794ISI: 001316850500001Scopus ID: 2-s2.0-85203822923OAI: oai:DiVA.org:kth-353970DiVA, id: diva2:1901046
Note

QC 20241007

Available from: 2024-09-25 Created: 2024-09-25 Last updated: 2024-10-07Bibliographically approved

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