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Melt processing of chemically modified cellulosic fibres with only water as plasticiser: Effects of moisture content and processing temperature
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fibre Technology. ..ORCID iD: 0000-0001-6167-6432
Chalmers Univ Technol, Dept Ind & Mat Sci, SE-41296 Gothenburg, Sweden.;Chalmers Univ Technol, ProDAC Proc Dialcohol Cellulose Prod, SE-41296 Gothenburg, Sweden..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fibre Technology. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center. ..ORCID iD: 0000-0002-7410-0333
2025 (English)In: Carbohydrate Polymers, ISSN 0144-8617, E-ISSN 1879-1344, Vol. 348, article id 122891Article in journal (Refereed) Published
Abstract [en]

To replace petroleum-derived polymers with cellulose fibres, it is desirable to have the option of melt processing. However, upon heating, cellulose degradation typically starts before the material reaches its softening temperature. Alternatives to plastics should also, ideally, be recyclable via existing recycling streams. Here, we address the problem of melt processing cellulose as fibres while preserving recyclability. Native cellulose fibres were partially modified to dialcohol cellulose to impart thermoplastic characteristics. We demonstrate melt processing of these modified fibres with only water as plasticiser. Processability was investigated at selected processing temperatures and initial moisture content by monitoring the axial force of the extruder screws as a rheological indicator. The effects on molecular structure, fibre morphology and material properties were characterised by NMR spectroscopy, microscopy, tensile testing, fibre morphology analysis and X-ray diffraction. When comparing the melt-processed extrudate with handsheets, the already exceptional ductility was further increased. Moderate losses in tensile strength and stiffness were observed and are attributable to a loss of crystallinity and fibre shortening. This is the first report of strong and durable extrudates using cellulosic fibres as the only feedstock. Finally, the potential for recycling the processed material with unmodified fibres by paper recycling procedures was demonstrated.

Place, publisher, year, edition, pages
Elsevier BV , 2025. Vol. 348, article id 122891
Keywords [en]
Cellulose, Dialcohol cellulose, Fibre modification, Fibre plasticisation, Melt processing
National Category
Polymer Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-356475DOI: 10.1016/j.carbpol.2024.122891ISI: 001348212200001PubMedID: 39567128Scopus ID: 2-s2.0-85207206219OAI: oai:DiVA.org:kth-356475DiVA, id: diva2:1914393
Note

QC 20241119

Available from: 2024-11-19 Created: 2024-11-19 Last updated: 2025-05-27Bibliographically approved

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Engel, EmileLarsson, Per A.

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