The Strength Evolution Mechanism of Cold-Pressed and Heat-Treated Carbon-Bearing Lumps During Reduction ProcessShow others and affiliations
2025 (English)In: Metallurgical and materials transactions. B, process metallurgy and materials processing science, ISSN 1073-5615, E-ISSN 1543-1916, Vol. 56, no 6, p. 6957-6966Article in journal (Refereed) Published
Abstract [en]
Under the demand for green and efficient development of the steel industry, cold-pressed and heat-treated carbon-containing lumps (CCLs) have emerged as key materials for optimizing the blast furnace burden structures. However, the strength evolution mechanism of CCLs during high-temperature reduction process has not well understood. In this study, biomass-based CCLs were prepared by cold-pressed and medium-low-temperature heat treatment. The evolution law and micro-mechanism of lump strength during the reduction process at 600 degrees C similar to 1200 degrees C were explored through compressive strength testing, X-ray diffraction, scanning electron microscopy, and van der Waals force theoretical calculations. The results show that the compressive strength of CCLs first decreases and then increases with the rise of temperature. The lowest strength occurs at 900 degrees C similar to 1000 degrees C due to the consumption of binders and the formation of FeO. At 1100 degrees C similar to 1200 degrees C, the interconnection of metallic iron crystals and the filling of pores by slag phase significantly improve the strength, with the maximum compressive strength exceeding 3000 N. During reduction, Fe3O4 is gradually reduced to FeO and metallic Fe. Metallic Fe is rapidly generated above 1000 degrees C and forms an interconnected crystal structure above 1100 degrees C. The micro-mechanism indicates that van der Waals force dominates the inter-particle bonding force, and the formation of metallic interconnected crystals at high temperatures enhances the mechanical interlocking and metallurgical bonding between particles. This study provides a theoretical basis for the optimization of carbon-containing lump preparation technology and the regulation of high-temperature properties.
Place, publisher, year, edition, pages
Springer Nature , 2025. Vol. 56, no 6, p. 6957-6966
National Category
Metallurgy and Metallic Materials
Identifiers
URN: urn:nbn:se:kth:diva-375002DOI: 10.1007/s11663-025-03819-xISI: 001596417600001Scopus ID: 2-s2.0-105018814842OAI: oai:DiVA.org:kth-375002DiVA, id: diva2:2026223
Note
QC 20260108
2026-01-082026-01-082026-01-08Bibliographically approved